7.E: El enlace químico y la geometría molecular (Ejercicios)

7.1: Enlace iónico

Q7.1.1

¿Un catión gana protones para formar una carga positiva o pierde electrones?

S7.1.1

Los protones del núcleo no cambian durante las reacciones químicas normales. Solo se mueven los electrones externos. Cargas positivas

se forman cuando se pierden electrones.

Q7.1.2

El sulfato de hierro (III) [Fe₂(SO₄)₃] está compuesto de Fe³⁺ y  \(\ce{SO4^2-}\ iones. Explique por qué no se carga una muestra de sulfato de hierro (III)

Q7.1.3

¿Cuál de los siguientes átomos se esperaría que forme iones negativos en compuestos iónicos binarios y cuál sería se espera que formen iones positivos: P, I, Mg, Cl, In, Cs, O, Pb, Co?

S7.1.3

P, I, Cl y O formarían aniones porque no son metales. Mg, In, Cs, Pb y Co formarían cationes porque son rieles

Q7.1.4

Which of the following atoms would be expected to form negative ions in binary ionic compounds and which would be expected to form positive ions: Br, Ca, Na, N, F, Al, Sn, S, Cd?

Q7.1.5

Predecir la carga de los iones monoatómicos formados a partir de los siguientes átomos en compuestos iónicos binarios:

A. P

B. Mg

C. Al

D. O

E. Cl

F. C

S7.1.5

P^3–; Mg²⁺; Al³⁺; O^2–; Cl^–; Cs⁺

Q7.1.6

Predecir la carga de los iones monoatómicos formados a partir de los siguientes átomos en compuestos iónicos binarios

1. Sr
2. K
3. N
4. S
5. In

S7.1.6

1. I^-
2. Sr²⁺
3. K⁺
4. N^3-
5. S^2-
6. In³⁺

Q7.1.7

Escriba la configuración electrónica para cada uno de los siguientes iones:

1. As^3–
2. I^–
3. Be²⁺
4. Cd²⁺
5. O^2–
6. Ga³⁺
7. Li⁺
8. (h) N^3–
9. (i) Sn²⁺
10. (j) Co²⁺
11. (k) Fe²⁺
12. (l) As³⁺

S7.1.7

[Ar]4s²3d¹⁰4p⁶; [Kr]4d¹⁰5s²5p⁶ 1s² [Kr]4d¹⁰; [He]2s²2p⁶; [Ar]3d¹⁰; 1s² (h) [He]2s²2p⁶ (i) [Kr]4d¹⁰5s² (j) [Ar]3d⁷ (k) [Ar]3d⁶, (l) [Ar]3d¹⁰4s²

Q7.1.8

Escriba la configuración electrónica de los iones monoatómicos formados a partir de los siguientes elementos (que forman la mayor concentración de iones monoatómicos en agua de mar):

1. Cl
2. Na
3. Mg
4. Ca
5. K
6. Br
7. Sr
8. (h) F

Q7.1.9

Escriba la configuración electrónica completa para cada uno de los siguientes átomos y para el ion monoatómico que se encuentra en binario iónico compuestos que contienen el elemento

1. Al
2. Br
3. Sr
4. Li
5. As
6. S

S7.1.9

1s²2s²2p⁶3s²3p¹; Al³⁺: 1s²2s²2p⁶; 1s²2s²2p⁶3s²3p⁶3d¹⁰4s²4p⁵; 1s²2s²2p⁶3s²3p⁶3d¹⁰4s²4p⁶; 1s²2s²2p⁶3s²3p⁶3d¹⁰4s²4p⁶5s²;

Sr²⁺: 1s²2s²2p⁶3s²3p⁶3d¹⁰4s²4p⁶; 1s²2s¹;

Li⁺: 1s²; 1s²2s²2p⁶3s²3p⁶3d¹⁰4s²4p³; 1s²2s²2p⁶3s²3p⁶3d¹⁰4s²4p⁶; 1s²2s²2p⁶3s²3p⁴; 1s²2s²2p⁶3s²3p⁶

Q7.1.10

A partir de las etiquetas de varios productos comerciales, prepare una lista de seis compuestos iónicos en los productos. Para cada compuesto, escribe la fórmula. (Es posible que deba buscar algunas fórmulas en una referencia adecuada).

7.3: Covalent Bonding

¿Por qué es incorrecto hablar de una molécula de NaCl sólido?

El NaCl consiste en iones discretos dispuestos en una red cristalina, no moléculas unidas covalentemente.

¿Qué información puede utilizar para predecir si un enlace entre dos átomos es covalente o iónico?

Predecir cuáles de los siguientes compuestos son iónicos y cuáles son covalentes, según la ubicación de sus átomos constituyentes en la tabla periodica

1. Cl₂CO
2. MnO
3. NCl₃
4. CoBr₂
5. K₂S
6. CO
7. CaF₂
8. (h) HI
9. (i) CaO
10. (j) IBr
11. (k) CO₂

iónico:: (b), (d), (e), (g), y (i);  covalente: (a), (c), (f), (h), (j), and (k)

Explique la diferencia entre un enlace covalente no polar, un enlace covalente polar y un enlace iónico.

A partir de su posición en la tabla periódica, determine qué átomo de cada par es más electronegativo:

1. Br o Cl
2. N o O
3. S o O
4. P o S
5. Si o N
6. Ba o P
7. N o K

Cl; O; O; S; N; P; N

A partir de su posición en la tabla periódica, determine qué átomo de cada par es más electronegativo:

1. N or P
2. N or Ge
3. S or F
4. Cl or S
5. H or C
6. Se or P
7. C or Si

Desde sus posiciones en la tabla periódica, organice los átomos en cada una de las siguientes series en orden creciente electronegatividad:

1. C, F, H, N, O
2. Br, Cl, F, H, I
3. F, H, O, P, S
4. Al, H, Na, O, P
5. Ba, H, N, O, As

H, C, N, O, F; H, I, Br, Cl, F; H, P, S, O, F; Na, Al, H, P, O; Ba, H, As, N, O

Desde sus posiciones en la tabla periódica, organice los átomos en cada una de las siguientes series en orden creciente electronegatividad:

1. As, H, N, P, Sb
2. Cl, H, P, S, Si
3. Br, Cl, Ge, H, Sr
4. Ca, H, K, N, Si
5. Cl, Cs, Ge, H, Sr

¿Qué átomos pueden unirse al azufre para producir una carga parcial positiva en el átomo de azufre?

N, O, F, and Cl

¿Cuál es el enlace más polar?

1. C–C
2. C–H
3. N–H
4. O–H
5. Se–H

Identifique el enlace más polar en cada uno de los siguientes pares de enlaces:

1. HF or HCl
2. NO or CO
3. SH or OH
4. PCl or SCl
5. CH or NH
6. SO or PO
7. CN or NN

HF; CO; OH; PCl; NH; PO; CN

¿Cuáles de las siguientes moléculas o iones contienen enlaces polares?

1. O₃
2. S₈
3. \(\ce{O2^2-}\)
4. \(\ce{NO3-}\)
5. CO₂
6. H₂S
7. \(\ce{BH4-}\)

7.4: Símbolos y estructuras de Lewis

Q7.4.1

Escriba los símbolos de Lewis para cada uno de los siguientes iones

1. As^3–
2. I^–
3. Be²⁺
4. O^2–
5. Ga³⁺
6. Li⁺
7. N^3–

S7.4.1

ocho electrones:        

 

ocho electrones:       

 

sin electrones                                        Be²⁺;

ocho electrones:       

 

sin electrones                                         Ga³⁺;

sin electrones                                          Li⁺;

ocho electrones:         

 

Q7.4.2

Muchos iones monoatómicos se encuentran en el agua de mar, incluidos los iones formados a partir de la siguiente lista de elementos. Escribe el Lewis símbolos para los iones monoatómicos formados a partir de los siguientes elementos:

1. Cl
2. Na
3. Mg
4. Ca
5. K
6. Br
7. Sr
8. F

Q7.4.3

Escriba los símbolos de Lewis de los iones en cada uno de los siguientes compuestos iónicos y los símbolos de Lewis del átomo del cual se forman:

1. MgS
2. Al₂O₃
3. GaCl₃
4. K₂O
5. Li₃N
6. KF

(a)

;

(b)

;

(c)

;

(d)

;

(e)

;

(f)

En las estructuras de Lewis enumeradas aquí, M y X representan varios elementos en el tercer período de la tabla periódica. Escribe el fórmula de cada compuesto usando los símbolos químicos de cada elemento:

(a)

(b)

(c)

(d)

Escriba la estructura de Lewis para la molécula diatómica P, una forma inestable de fósforo que se encuentra en el fósforo de alta temperatura vapor

Escriba estructuras de Lewis para lo siguiente:

1. H₂
2. HBr
3. PCl₃
4. SF₂
5. H₂CCH₂
6. HNNH
7. H₂CNH
8. (h) NO^–
9. (i) N₂
10. (j) CO
11. (k) CN^–

Escriba estructuras de Lewis para lo siguiente:

1. O₂
2. H₂CO
3. AsF₃
4. ClNO
5. SiCl₄
6. H₃O⁺
7. \(\ce{NH4+}\)
8. (h) \(\ce{BF4-}\)
9. (i) HCCH
10. (j) ClCN
11. (k) \(\ce{C2^2+}\)

(a)

En este caso, la estructura de Lewis es inadecuada para representar el hecho de que los estudios experimentales han mostrado dos electrones desapareados en cada molécula de oxígeno

(b)

;

(c)

;

(d)

;

(e)

;

(f)

;

(g)

;

(h)

;

(i)

;

(j)

;

(k)

Escriba estructuras de Lewis para lo siguiente:

1. ClF₃
2. PCl₅
3. BF₃
4. \(\ce{PF6-}\)

Escriba estructuras de Lewis para lo siguiente:

1. SeF₆
2. XeF₄
3. \(\ce{SeCl3+}\)
4. Cl₂BBCl₂ (contiene un enlace B–B )

SeF₆:

;

XeF₄:

;

\(\ce{SeCl3+}\):

;

Cl₂BBCl₂:

Escriba estructuras de Lewis para lo siguiente:

1. \(\ce{PO4^3-}\)
2. \(\ce{ICl4-}\)
3. \(\ce{SO3^2-}\)
4. HONO

Corrija la siguiente afirmación: “Los enlaces en el PbCl₂ sólido son iónicos; el enlace en una molécula de HCl es covalente. Por lo tanto, todos los electrones de valencia en PbCl₂ se encuentran en los iones Cl^– , y todos los electrones de valencia en una molécula de HCl se comparten entre los átomos de H y Cl ".

Se transfieren dos electrones de valencia por átomo de Pb a los átomos de Cl; el ion Pb²⁺ resultante tiene una configuración de capa de valencia de 6s². Dos de los electrones de valencia en la molécula de HCl se comparten, y los otros seis están ubicados en el átomo de Cl como pares solitarios de electrones.

Escriba estructuras de Lewis para las siguientes moléculas o iones

1. SbH₃
2. XeF₂
3. Se₈ (una molécula cíclica con un anillo de ocho átomos de Se)

El metanol, H₃COH, se usa como combustible en algunos autos de carrera. El etanol, H₃COH, se utiliza ampliamente como combustible de motor en Brasil. Ambas cosas el metanol y el etanol producen CO₂ y H₂O cuando se queman. Escribe las ecuaciones químicas para estas reacciones de combustión. utilizando estructuras de Lewis en lugar de fórmulas químicas

Many planets in our solar system contain organic chemicals including methane (CH₄) and traces of ethylene (C₂H₄), ethane (C₂H₆), propyne (H₃CCCH), and diacetylene (HCCCCH). Write the Lewis structures for each of these molecules.

Carbon tetrachloride was formerly used in fire extinguishers for electrical fires. It is no longer used for this purpose because of the formation of the toxic gas phosgene, Cl₂CO. Write the Lewis structures for carbon tetrachloride and phosgene.

Identify the atoms that correspond to each of the following electron configurations. Then, write the Lewis symbol for the common ion formed from each atom:

1. 1s²2s²2p⁵
2. 1s²2s²2p⁶3s²
3. 1s²2s²2p⁶3s²3p⁶4s²3d¹⁰
4. 1s²2s²2p⁶3s²3p⁶4s²3d¹⁰4p⁴
5. 1s²2s²2p⁶3s²3p⁶4s²3d¹⁰4p¹

The arrangement of atoms in several biologically important molecules is given here. Complete the Lewis structures of these molecules by adding multiple bonds and lone pairs. Do not add any more atoms.

the amino acid serine:

urea:

pyruvic acid:

uracil:

carbonic acid:

(a)

;

(b)

;

(c)

;

(d)

;

(e)

A compound with a molar mass of about 28 g/mol contains 85.7% carbon and 14.3% hydrogen by mass. Write the Lewis structure for a molecule of the compound.

A compound with a molar mass of about 42 g/mol contains 85.7% carbon and 14.3% hydrogen by mass. Write the Lewis structure for a molecule of the compound.

Two arrangements of atoms are possible for a compound with a molar mass of about 45 g/mol that contains 52.2% C, 13.1% H, and 34.7% O by mass. Write the Lewis structures for the two molecules.

How are single, double, and triple bonds similar? How do they differ?

Each bond includes a sharing of electrons between atoms. Two electrons are shared in a single bond; four electrons are shared in a double bond; and six electrons are shared in a triple bond.

7.5: Formal Charges and Resonance

Write resonance forms that describe the distribution of electrons in each of these molecules or ions.

1. selenium dioxide, OSeO
2. nitrate ion, \(\ce{NO3-}\)
3. nitric acid, HNO₃ (N is bonded to an OH group and two O atoms)
4. benzene, C₆H₆:

the formate ion:

Write resonance forms that describe the distribution of electrons in each of these molecules or ions.

1. sulfur dioxide, SO₂
2. carbonate ion, \(\ce{CO3^2-}\)
3. hydrogen carbonate ion, \(\ce{HCO3-}\) (C is bonded to an OH group and two O atoms)
4. pyridine:

the allyl ion:

(a)

;

(b)

;

(c)

;

(d)

;

(e)

Write the resonance forms of ozone, O₃, the component of the upper atmosphere that protects the Earth from ultraviolet radiation.

Sodium nitrite, which has been used to preserve bacon and other meats, is an ionic compound. Write the resonance forms of the nitrite ion, \(\ce{NO2-}\).

In terms of the bonds present, explain why acetic acid, CH₃CO₂H, contains two distinct types of carbon-oxygen bonds, whereas the acetate ion, formed by loss of a hydrogen ion from acetic acid, only contains one type of carbon-oxygen bond. The skeleton structures of these species are shown:

Write the Lewis structures for the following, and include resonance structures where appropriate. Indicate which has the strongest carbon-oxygen bond.

1. CO₂
2. CO

(a)

(b)

CO has the strongest carbon-oxygen bond because there is a triple bond joining C and O. CO₂ has double bonds.

Toothpastes containing sodium hydrogen carbonate (sodium bicarbonate) and hydrogen peroxide are widely used. Write Lewis structures for the hydrogen carbonate ion and hydrogen peroxide molecule, with resonance forms where appropriate.

Determine the formal charge of each element in the following:

1. HCl
2. CF₄
3. PCl₃
4. PF₅

H: 0, Cl: 0; C: 0, F: 0; P: 0, Cl 0; P: 0, F: 0

Determine the formal charge of each element in the following:

1. H₃O⁺
2. \(\ce{SO4^2-}\)
3. NH₃
4. \(\ce{O2^2-}\)
5. H₂O₂

Calculate the formal charge of chlorine in the molecules Cl₂, BeCl₂, and ClF₅.

Cl in Cl₂: 0; Cl in BeCl₂: 0; Cl in ClF₅: 0

Calculate the formal charge of each element in the following compounds and ions:

1. F₂CO
2. NO^–
3. \(\ce{BF4-}\)
4. \(\ce{SnCl3-}\)
5. H₂CCH₂
6. ClF₃
7. SeF₆
8. (h) \(\ce{PO4^3-}\)

Draw all possible resonance structures for each of these compounds. Determine the formal charge on each atom in each of the resonance structures:

1. O₃
2. SO₂
3. \(\ce{NO2-}\)
4. \(\ce{NO3-}\)

;

(b)

;

(c)

;

(d)

Based on formal charge considerations, which of the following would likely be the correct arrangement of atoms in nitrosyl chloride: ClNO or ClON?

Based on formal charge considerations, which of the following would likely be the correct arrangement of atoms in hypochlorous acid: HOCl or OClH?

HOCl

Based on formal charge considerations, which of the following would likely be the correct arrangement of atoms in sulfur dioxide: OSO or SOO?

Draw the structure of hydroxylamine, H₃NO, and assign formal charges; look up the structure. Is the actual structure consistent with the formal charges?

The structure that gives zero formal charges is consistent with the actual structure:

Iodine forms a series of fluorides (listed here). Write Lewis structures for each of the four compounds and determine the formal charge of the iodine atom in each molecule:

1. IF
2. IF₃
3. IF₅
4. IF₇

Write the Lewis structure and chemical formula of the compound with a molar mass of about 70 g/mol that contains 19.7% nitrogen and 80.3% fluorine by mass, and determine the formal charge of the atoms in this compound.

NF₃;

Which of the following structures would we expect for nitrous acid? Determine the formal charges:

Sulfuric acid is the industrial chemical produced in greatest quantity worldwide. About 90 billion pounds are produced each year in the United States alone. Write the Lewis structure for sulfuric acid, H₂SO₄, which has two oxygen atoms and two OH groups bonded to the sulfur.

7.6: Strengths of Ionic and Covalent Bonds

Which bond in each of the following pairs of bonds is the strongest?

1. C–C or \(\mathrm{C=C}\)
2. C–N or \(\mathrm{C≡N}\)
3. \(\mathrm{C≡O}\) or \(\mathrm{C=O}\)
4. H–F or H–Cl
5. C–H or O–H
6. C–N or C–O

Using the bond energies in Table, determine the approximate enthalpy change for each of the following reactions:

1. \(\ce{H2}(g)+\ce{Br2}(g)⟶\ce{2HBr}(g)\)
2. \(\ce{CH4}(g)+\ce{I2}(g)⟶\ce{CH3I}(g)+\ce{HI}(g)\)
3. (c) \(\ce{C2H4}(g)+\ce{3O2}(g)⟶\ce{2CO2}(g)+\ce{2H2O}(g)\)

1. −114 kJ;
2. 30 kJ;
3. (c) −1055 kJ

Using the bond energies in Table, determine the approximate enthalpy change for each of the following reactions:

1. \(\ce{Cl2}(g)+\ce{3F2}(g)⟶\ce{2ClF3}(g)\)
2. \(\mathrm{H_2C=CH_2}(g)+\ce{H2}(g)⟶\ce{H3CCH3}(g)\)
3. (c) \(\ce{2C2H6}(g)+\ce{7O2}(g)⟶\ce{4CO2}(g)+\ce{6H2O}(g)\)

When a molecule can form two different structures, the structure with the stronger bonds is usually the more stable form. Use bond energies to predict the correct structure of the hydroxylamine molecule:

The greater bond energy is in the figure on the left. It is the more stable form.

How does the bond energy of HCldiffer from the standard enthalpy of formation of HCl(g)?

Using the standard enthalpy of formation data in Appendix G, show how the standard enthalpy of formation of HCl(g) can be used to determine the bond energy.

\(\ce{HCl}(g)⟶\dfrac{1}{2}\ce{H2}(g)+\dfrac{1}{2}\ce{Cl2}(g)\hspace{20px}ΔH^\circ_1=−ΔH^\circ_{\ce f[\ce{HCl}(g)]}\\
\dfrac{1}{2}\ce{H2}(g)⟶\ce{H}(g)\hspace{105px}ΔH^\circ_2=ΔH^\circ_{\ce f[\ce H(g)]}\\
\underline{\dfrac{1}{2}\ce{Cl2}(g)⟶\ce{Cl}(g)\hspace{99px}ΔH^\circ_3=ΔH^\circ_{\ce f[\ce{Cl}(g)]}}\\
\ce{HCl}(g)⟶\ce{H}(g)+\ce{Cl}(g)\hspace{58px}ΔH^\circ_{298}=ΔH^\circ_1+ΔH^\circ_2+ΔH^\circ_3\)

\(\begin{align}
D_\ce{HCl}=ΔH^\circ_{298}&=ΔH^\circ_{\ce f[\ce{HCl}(g)]}+ΔH^\circ_{\ce f[\ce H(g)]}+ΔH^\circ_{\ce f[\ce{Cl}(g)]}\\
&=\mathrm{−(−92.307\:kJ)+217.97\:kJ+121.3\:kJ}\\
&=\mathrm{431.6\:kJ}
\end{align}\)

Using the standard enthalpy of formation data in Appendix G, calculate the bond energy of the carbon-sulfur double bond in CS₂.

Using the standard enthalpy of formation data in Appendix G, determine which bond is stronger: the S–F bond in SF₄(g) or in SF₆(g)?

The S–F bond in SF₄ is stronger.

Using the standard enthalpy of formation data in Appendix G, determine which bond is stronger: the P–Cl bond in PCl₃(g) or in PCl₅(g)?

Complete the following Lewis structure by adding bonds (not atoms), and then indicate the longest bond:

The C–C single bonds are longest.

Use the bond energy to calculate an approximate value of ΔH for the following reaction. Which is the more stable form of FNO₂?

Use principles of atomic structure to answer each of the following:¹

1. The radius of the Ca atom is 197 pm; the radius of the Ca²⁺ ion is 99 pm. Account for the difference.
2. The lattice energy of CaO(s) is –3460 kJ/mol; the lattice energy of K₂O is –2240 kJ/mol. Account for the difference.
3. (c) Given these ionization values, explain the difference between Ca and K with regard to their first and second ionization energies.

Element	First Ionization Energy (kJ/mol)	Second Ionization Energy (kJ/mol)
K	419	3050
Ca	590	1140

The first ionization energy of Mg is 738 kJ/mol and that of Al is 578 kJ/mol. Account for this difference.

When two electrons are removed from the valence shell, the Ca radius loses the outermost energy level and reverts to the lower n = 3 level, which is much smaller in radius. The +2 charge on calcium pulls the oxygen much closer compared with K, thereby increasing the lattice energy relative to a less charged ion. (c) Removal of the 4s electron in Ca requires more energy than removal of the 4s electron in K because of the stronger attraction of the nucleus and the extra energy required to break the pairing of the electrons. The second ionization energy for K requires that an electron be removed from a lower energy level, where the attraction is much stronger from the nucleus for the electron. In addition, energy is required to unpair two electrons in a full orbital. For Ca, the second ionization potential requires removing only a lone electron in the exposed outer energy level. In Al, the removed electron is relatively unprotected and unpaired in a p orbital. The higher energy for Mg mainly reflects the unpairing of the 2s electron.

The lattice energy of LiF is 1023 kJ/mol, and the Li–F distance is 200.8 pm. NaF crystallizes in the same structure as LiF but with a Na–F distance of 231 pm. Which of the following values most closely approximates the lattice energy of NaF: 510, 890, 1023, 1175, or 4090 kJ/mol? Explain your choice.

For which of the following substances is the least energy required to convert one mole of the solid into separate ions?

1. MgO
2. SrO
3. (c) KF
4. CsF
5. MgF₂

(d)

The reaction of a metal, M, with a halogen, X₂, proceeds by an exothermic reaction as indicated by this equation: \(\ce{M}(s)+\ce{X2}(g)⟶\ce{MX2}(s)\). For each of the following, indicate which option will make the reaction more exothermic. Explain your answers.

1. a large radius vs. a small radius for M⁺²
2. a high ionization energy vs. a low ionization energy for M
3. (c) an increasing bond energy for the halogen
4. a decreasing electron affinity for the halogen
5. an increasing size of the anion formed by the halogen

The lattice energy of LiF is 1023 kJ/mol, and the Li–F distance is 201 pm. MgO crystallizes in the same structure as LiF but with a Mg–O distance of 205 pm. Which of the following values most closely approximates the lattice energy of MgO: 256 kJ/mol, 512 kJ/mol, 1023 kJ/mol, 2046 kJ/mol, or 4008 kJ/mol? Explain your choice.

4008 kJ/mol; both ions in MgO have twice the charge of the ions in LiF; the bond length is very similar and both have the same structure; a quadrupling of the energy is expected based on the equation for lattice energy

Which compound in each of the following pairs has the larger lattice energy? Note: Mg²⁺ and Li⁺ have similar radii; O^2– and F^– have similar radii. Explain your choices.

1. MgO or MgSe
2. LiF or MgO
3. (c) Li₂O or LiCl
4. Li₂Se or MgO

Which compound in each of the following pairs has the larger lattice energy? Note: Ba²⁺ and

K⁺ have similar radii; S^2– and Cl^– have similar radii. Explain your choices.

1. K₂O or Na₂O
2. K₂S or BaS
3. (c) KCl or BaS
4. BaS or BaCl₂

Na₂O; Na⁺ has a smaller radius than K⁺; BaS; Ba has a larger charge than K; (c) BaS; Ba and S have larger charges; BaS; S has a larger charge

Which of the following compounds requires the most energy to convert one mole of the solid into separate ions?

1. MgO
2. SrO
3. (c) KF
4. CsF
5. MgF₂

Which of the following compounds requires the most energy to convert one mole of the solid into separate ions?

1. K₂S
2. K₂O
3. (c) CaS
4. Cs₂S
5. CaO

(e)

The lattice energy of KF is 794 kJ/mol, and the interionic distance is 269 pm. The Na–F

distance in NaF, which has the same structure as KF, is 231 pm. Which of the following values is the closest approximation of the lattice energy of NaF: 682 kJ/mol, 794 kJ/mol, 924 kJ/mol, 1588 kJ/mol, or 3175 kJ/mol? Explain your answer.

7.7: Molecular Structure and Polarity

Explain why the HOH molecule is bent, whereas the HBeH molecule is linear.

The placement of the two sets of unpaired electrons in water forces the bonds to assume a tetrahedral arrangement, and the resulting HOH molecule is bent. The HBeH molecule (in which Be has only two electrons to bond with the two electrons from the hydrogens) must have the electron pairs as far from one another as possible and is therefore linear.

What feature of a Lewis structure can be used to tell if a molecule’s (or ion’s) electron-pair geometry and molecular structure will be identical?

Explain the difference between electron-pair geometry and molecular structure.

Space must be provided for each pair of electrons whether they are in a bond or are present as lone pairs. Electron-pair geometry considers the placement of all electrons. Molecular structure considers only the bonding-pair geometry.

Why is the H–N–H angle in NH₃ smaller than the H–C–H bond angle in CH₄? Why is the H–N–H angle in \(\ce{NH4+}\) identical to the H–C–H bond angle in CH₄?

Explain how a molecule that contains polar bonds can be nonpolar.

As long as the polar bonds are compensated (for example. two identical atoms are found directly across the central atom from one another), the molecule can be nonpolar.

As a general rule, MX_n molecules (where M represents a central atom and X represents terminal atoms; n = 2 – 5) are polar if there is one or more lone pairs of electrons on M. NH₃ (M = N, X = H, n = 3) is an example. There are two molecular structures with lone pairs that are exceptions to this rule. What are they?

Predict the electron pair geometry and the molecular structure of each of the following molecules or ions:

1. SF₆
2. PCl₅
3. (c) BeH₂
4. \(\ce{CH3+}\)

1. Both the electron geometry and the molecular structure are octahedral.
2. Both the electron geometry and the molecular structure are trigonal bipyramid.
3. (c) Both the electron geometry and the molecular structure are linear.
4. Both the electron geometry and the molecular structure are trigonal planar.

Identify the electron pair geometry and the molecular structure of each of the following molecules or ions:

1. \(\ce{IF6+}\)
2. CF₄
3. (c) BF₃
4. \(\ce{SiF5-}\)
5. BeCl₂

What are the electron-pair geometry and the molecular structure of each of the following molecules or ions?

1. ClF₅
2. \(\ce{ClO2-}\)
3. (c) \(\ce{TeCl4^2-}\)
4. PCl₃
5. SeF₄
6. \(\ce{PH2-}\)

electron-pair geometry: octahedral, molecular structure: square pyramidal; electron-pair geometry: tetrahedral, molecular structure: bent; (c) electron-pair geometry: octahedral, molecular structure: square planar; electron-pair geometry: tetrahedral, molecular structure: trigonal pyramidal; electron-pair geometry: trigonal bypyramidal, molecular structure: seesaw; electron-pair geometry: tetrahedral, molecular structure: bent (109°)

Predict the electron pair geometry and the molecular structure of each of the following ions:

1. H₃O⁺
2. \(\ce{PCl4-}\)
3. (c) \(\ce{SnCl3-}\)
4. \(\ce{BrCl4-}\)
5. ICl₃
6. XeF₄
7. (g) SF₂

Identify the electron pair geometry and the molecular structure of each of the following molecules:

1. ClNO (N is the central atom)
2. CS₂
3. (c) Cl₂CO (C is the central atom)
4. Cl₂SO (S is the central atom)
5. SO₂F₂ (S is the central atom)
6. XeO₂F₂ (Xe is the central atom)
7. (g) \(\ce{ClOF2+}\) (Cl is the central atom)

electron-pair geometry: trigonal planar, molecular structure: bent (120°); electron-pair geometry: linear, molecular structure: linear; (c) electron-pair geometry: trigonal planar, molecular structure: trigonal planar; electron-pair geometry: tetrahedral, molecular structure: trigonal pyramidal; electron-pair geometry: tetrahedral, molecular structure: tetrahedral; electron-pair geometry: trigonal bipyramidal, molecular structure: seesaw; (g) electron-pair geometry: tetrahedral, molecular structure: trigonal pyramidal

Predict the electron pair geometry and the molecular structure of each of the following:

1. IOF₅ (I is the central atom)
2. POCl₃ (P is the central atom)
3. (c) Cl₂SeO (Se is the central atom)
4. ClSO⁺ (S is the central atom)
5. F₂SO (S is the central atom)
6. \(\ce{NO2-}\)
7. (g) \(\ce{SiO4^4-}\)

Which of the following molecules and ions contain polar bonds? Which of these molecules and ions have dipole moments?

1. ClF₅
2. \(\ce{ClO2-}\)
3. (c) \(\ce{TeCl4^2-}\)
4. PCl₃
5. SeF₄
6. \(\ce{PH2-}\)
7. (g) XeF₂

All of these molecules and ions contain polar bonds. Only ClF₅, \(\ce{ClO2-}\), PCl₃, SeF₄, and \(\ce{PH2-}\) have dipole moments.

Which of the molecules and ions in Exercise contain polar bonds? Which of these molecules and ions have dipole moments?

1. H₃O⁺
2. \(\ce{PCl4-}\)
3. (c) \(\ce{SnCl3-}\)
4. \(\ce{BrCl4-}\)
5. ICl₃
6. XeF₄
7. (g) SF₂

Which of the following molecules have dipole moments?

1. CS₂
2. SeS₂
3. (c) CCl₂F₂
4. PCl₃ (P is the central atom)
5. ClNO (N is the central atom)

SeS₂, CCl₂F₂, PCl₃, and ClNO all have dipole moments.

Identify the molecules with a dipole moment:

1. SF₄
2. CF₄
3. (c) Cl₂CCBr₂
4. CH₃Cl
5. H₂CO

The molecule XF₃ has a dipole moment. Is X boron or phosphorus?

P

The molecule XCl₂ has a dipole moment. Is X beryllium or sulfur?

Is the Cl₂BBCl₂ molecule polar or nonpolar?

nonpolar

There are three possible structures for PCl₂F₃ with phosphorus as the central atom. Draw them and discuss how measurements of dipole moments could help distinguish among them.

Describe the molecular structure around the indicated atom or atoms:

1. the sulfur atom in sulfuric acid, H₂SO₄ [(HO)₂SO₂]
2. the chlorine atom in chloric acid, HClO₃ [HOClO₂]
3. (c) the oxygen atom in hydrogen peroxide, HOOH
4. the nitrogen atom in nitric acid, HNO₃ [HONO₂]
5. the oxygen atom in the OH group in nitric acid, HNO₃ [HONO₂]
6. the central oxygen atom in the ozone molecule, O₃
7. (g) each of the carbon atoms in propyne, CH₃CCH
8. (h) the carbon atom in Freon, CCl₂F₂
9. (i) each of the carbon atoms in allene, H₂CCCH₂

tetrahedral; trigonal pyramidal; (c) bent (109°); trigonal planar; bent (109°); bent (109°); (g) CH₃CCH tetrahedral, CH₃CCH linear; (h) tetrahedral; (i) H₂CCCH₂ linear; H₂CCCH₂ trigonal planar

Draw the Lewis structures and predict the shape of each compound or ion:

1. CO₂
2. \(\ce{NO2-}\)
3. (c) SO₃
4. \(\ce{SO3^2-}\)

A molecule with the formula AB₂, in which A and B represent different atoms, could have one of three different shapes. Sketch and name the three different shapes that this molecule might have. Give an example of a molecule or ion for each shape.

A molecule with the formula AB₃, in which A and B represent different atoms, could have one of three different shapes. Sketch and name the three different shapes that this molecule might have. Give an example of a molecule or ion that has each shape.

Draw the Lewis electron dot structures for these molecules, including resonance structures where appropriate:

1. \(\ce{CS3^2-}\)
2. CS₂
3. (c) CS

predict the molecular shapes for \(\ce{CS3^2-}\) and CS₂ and explain how you arrived at your predictions

(a)

;

(b)

;

(c)

;

\(\ce{CS3^2-}\) includes three regions of electron density (all are bonds with no lone pairs); the shape is trigonal planar; CS₂ has only two regions of electron density (all bonds with no lone pairs); the shape is linear

What is the molecular structure of the stable form of FNO₂? (N is the central atom.)

A compound with a molar mass of about 42 g/mol contains 85.7% carbon and 14.3% hydrogen. What is its molecular structure?

The Lewis structure is made from three units, but the atoms must be rearranged:

Use the simulation to perform the following exercises for a two-atom molecule:

1. Adjust the electronegativity value so the bond dipole is pointing toward B. Then determine what the electronegativity values must be to switch the dipole so that it points toward A.
2. With a partial positive charge on A, turn on the electric field and describe what happens.
3. (c) With a small partial negative charge on A, turn on the electric field and describe what happens.
4. Reset all, and then with a large partial negative charge on A, turn on the electric field and describe what happens.

Use the simulation to perform the following exercises for a real molecule. You may need to rotate the molecules in three dimensions to see certain dipoles.

1. Sketch the bond dipoles and molecular dipole (if any) for O_3. Explain your observations.
2. Look at the bond dipoles for NH₃. Use these dipoles to predict whether N or H is more electronegative.
3. (c) Predict whether there should be a molecular dipole for NH₃ and, if so, in which direction it will point. Check the molecular dipole box to test your hypothesis.

The molecular dipole points away from the hydrogen atoms.

Use the Molecule Shape simulator to build a molecule. Starting with the central atom, click on the double bond to add one double bond. Then add one single bond and one lone pair. Rotate the molecule to observe the complete geometry. Name the electron group geometry and molecular structure and predict the bond angle. Then click the check boxes at the bottom and right of the simulator to check your answers.

Use the Molecule Shape simulator to explore real molecules. On the Real Molecules tab, select H₂O. Switch between the “real” and “model” modes. Explain the difference observed.

The structures are very similar. In the model mode, each electron group occupies the same amount of space, so the bond angle is shown as 109.5°. In the “real” mode, the lone pairs are larger, causing the hydrogens to be compressed. This leads to the smaller angle of 104.5°.

Use the Molecule Shape simulator to explore real molecules. On the Real Molecules tab, select “model” mode and S₂O. What is the model bond angle? Explain whether the “real” bond angle should be larger or smaller than the ideal model angle.