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    • https://espanol.libretexts.org/Quimica/Libro%3A_Qu%C3%ADmica_Org%C3%A1nica_con_%C3%A9nfasis_Biol%C3%B3gico_(Soderberg)/13%3A_Reacciones_con_intermediados_de_carbaniones_estabilizados_I/13.3%3A_Reacciones_de_isomerizaci%C3%B3n
      However, because there happens to be a hydroxyl group on C 1 , the carbonyl can form here as well as at C 2 . Notice that DHAP is achiral while GAP is chiral, and that a new chiral center is introduce...However, because there happens to be a hydroxyl group on C 1 , the carbonyl can form here as well as at C 2 . Notice that DHAP is achiral while GAP is chiral, and that a new chiral center is introduced at C 2 . The catalytic base abstracts the pro-R proton from behind the plane of the page, then gives the same proton back to C 2 , again from behind the plane of the page.

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