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6.13: Termodinámica

  • Page ID
    78850
    • John Moore, Jia Zhou, and Etienne Garand
    • University of Wisconsin

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    Termodinámica

    John Moore, Jia Zhou y Etienne Garand

    Valores termodinámicos para compuestos selectos

    en 298.15 K.

    Especies Δf H° (kJ/mol) S° (J K −1 mol −1) Δf G° (kJ/mol)
    Aluminio      
    Al (s) 0 28.275 0
    Al³+ (aq) 531 321.7 485
    AlCl₃ (s) 704.2 110.67 628.8
    Al₂O₃ (s, corindón) 1675.7 50.92 1582.3
    Argón      
    Ar (g) 0 154.843 0
    Ar (ac) 12.1 59.4 16.4
    Bario      
    Bacl₂ (s) 858.6 123.68 810.4
    BAo (s) 553.5 70.42 525.1
    BaseSO4 (s) 1473.2 132.2 1362.2
    BACO₃ (s) 1216.3 112.1 85.35
    Berilio      
    Ser (s) 0 9.5 0
    Ser (OH) ₂ (s) 902.5 51.9 815
    Bromo      
    Br (g) 111.884 175.022 82.396
    Br₂ (l) 0 152.231 0
    Br₂ (g) 30.907 245.463 3.110
    Br₂ (aq) 2.59 130.5 3.93
    Br- (aq) 121.55 82.4 103.96
    BrCl (g) 14.64 240.10 0.98
    BrF₃ (g) 255.6 292.53 229.43
    HBr (g) 36.40 198.695 53.45
    Calcio      
    Ca (s) 0 41.42 0
    Ca (g) 178.2 158.884 144.3
    Ca²+ (g) 1925.9
    Ca²+ (aq) 542.83 53.1 553.58
    CaC₂ (s) 59.8 69.96 64.9
    CaCO₃ (s, calcita) 1206.92 92.9 1128.79
    CaCl2 (s) 795.8 104.6 748.1
    CaF₂ 1219.6 68.87 1167.3
    CaH₂ (s) 186.2 42 147.2
    CaO (s) 635.09 39.75 604.03
    CA (s) 482.4 56.5 477.4
    Ca (OH) ₂ (s) 986.09 83.39 898.49
    Ca (OH) ₂ (aq) 1002.82 74.5 868.07
    CaSO4 (s) 1434.11 106.7 1321.79
    Carbono      
    C (s, grafito) 0 5.74 0
    C (s, diamante) 1.895 2.377 2.9
    C (g) 716.682 158.096 671.257
    CCl4 (l) 135.44 216.4 65.21
    CCl4 (g) 102.9 309.85 60.59
    CHCl₃ (l) 134.47 201.7 73.66
    CHCl₃ (g) 103.14 295.71 70.34
    CH4 (g, metano) 74.81 186.264 50.72
    C₂H₂ (g, etino) 226.73 200.94 209.2
    C₂H4 (g, eteno) 52.26 219.56 68.15
    C₂H6 (g, etano) 84.68 229.6 32.82
    C3H8 (g, propano) 103.8 269.9 23.49
    C4H10 (g, butano) 126.148 310.227 16.985
    C6H6 (l, benceno) 49.03 172.8 124.5
    C6H14 (l, hexano) 198.782 296.018 4.035
    C8H1-8 (g, octano) 208.447 466.835 16.718
    C8H18 (l, octano) 249.952 361.205 6.707
    CH3OH (l, metanol) 238.66 126.8 166.27
    CH3OH (g, metanol) 200.66 239.81 161.96
    CH3OH (ac, metanol) 245.931 133.1 175.31
    C2H5OH (l, etanol) 277.69 160.7 174.78
    C₂H5OH (g, etanol) 235.1 282.7 168.49
    C₂H5OH (ac, etanol) 288.3 148.5 181.64
    C6H1₂O6 (s, glucosa) 1274.4 235.9 917.2
    CH3COO- (aq) 486.01 86.6 369.31
    CH3COOH (aq) 485.76 178.7 396.46
    CH3COOH (l) 484.5 159.8 389.9
    CO (g) 110.525 197.674 137.168
    CO₂ (g) 393.509 213.74 394.359
    H₂CO₃ (aq) 699.65 187.4 623.08
    HCO3- (aq) 691.99 91.2 586.77
    CO3²—( aq) 677.14 56.9 527.81
    HCOO- (aq) 425.55 92.0 351.0
    HCOOH (aq) 425.43 163 372.3
    HCOOH (l) 424.72 128.95 361.35
    CS₂ (g) 117.36 237.84 67.12
    CS₂ (l) 89.70 151.34 65.27
    CoCl₂ (g) 218.8 283.53 204.6
    Cesio      
    Cs (s) 0 85.23 0
    Cs+ (g) 457.964
    CsCl (s) 443.04 101.17 414.53
    Cloro      
    Cl (g) 121.679 165.198 105.68
    CI- (g) 233.13
    Cl- (aq) 167.159 56.5 131.228
    Cl₂ (g) 0 223.066 0
    Cl₂ (aq) 23.4 121 6.94
    HCl (g) 92.307 186.908 95.299
    HCl (ac) 167.159 56.5 131.228
    ClO₂ (g) 102.5 256.84 120.5
    Cl₂O (g) 80.3 266.21 97.9
    ClO- (aq) 107.1 42.0 36.8
    HClO 120.9 142 79.9
    ClF₃ (g) 163.2 281.61 123.0
    Cromo      
    Cr (s) 0 23.77 0
    Cr₂O₃ (s) 1139.7 81.2 1058.1
    CrCl₃ (s) 556.5 123 486.1
    Cobre      
    Cu (s) 0 33.15 0
    CuO (s) 157.3 42.63 129.7
    CuCl₂ (s) 220.1 108.07 175.7
    CuSO4 (s) 771.36 109 661.8
    Flúor      
    F₂ (g) 0 202.78 0
    F (g) 78.99 158.754 61.91
    F- (g) 255.39
    F- (aq) 332.63 13.8 278.79
    HF (g) 271.1 173.779 273.2
    HF (aq, no ionizado) 320.08 88.7 296.82
    HF (aq, ionizado) 332.63 13.8 278.79
    Hidrógeno      
    H₂ (g) 0 130.684 0
    H2 (aq) 4.2 57.7 17.6
    HD (g) 0.318 143.801 1.464
    D₂ (g) 0 144.960 0
    H (g) 217.965 114.713 203.247
    H+ (g) 1536.202
    H+ (aq) 0 0 0
    OH- (aq) 229.994 10.75 157.244
    H2O (l) 285.83 69.91 237.129
    H2O (g) 241.818 188.825 228.572
    H2O₂ (l) 187.78 109.6 120.35
    H2O₂ (aq) 191.17 143.9 134.03
    HO₂- (aq) 160.33 23.8 67.3
    HDO (l) 289.888 79.29 241.857
    D2o (l) 294.600 75.94 243.439
    Yodo      
    I₂ (s) 0 116.135 0
    I₂ (g) 62.438 260.69 19.327
    I₂ (aq) 22.6 137.2 16.40
    I (g) 106.838 180.791 70.25
    I- (g) 197
    I- (aq) 55.19 111.3 51.57
    I3- (aq) 51.5 239.3 51.4
    HI (g) 26.48 206.594 1.70
    HI (aq, ionizado) 55.19 111.3 51.57
    SI (g) 95.65 236.17 118.51
    iCL (g) 17.78 247.551 5.46
    iCL (l) 23.89 135.1 13.58
    iBR (g) 40.84 258.773 3.69
    iCl₃ (s) 89.5 167.4 22.29
    Hierro      
    Fe (s) 0 27.78 0
    FeO (s, wustita) 266.27 57.49 245.12
    Fe₂O₃ (s, hematita) 824.2 87.4 742.2
    Fe3O4 (s, magnetita) 1118.4 146.4 1015.4
    FeCl₂ (s) 341.79 117.95 302.3
    FeCl₃ (s) 399.49 142.3 344
    FeS₂ (s, pirita) 178.2 52.93 166.9
    Fe (CO) 5 (l) 774 338.1 705.3
    Plomo      
    Pb (s) 0 64.81 0
    PbCl₂ (s) 359.41 136 314.1
    PbO (s, amarillo) 217.32 68.7 187.89
    PB (s) 100.4 91.2 98.7
    PbSO4 (s) 919.94 148.57 813.14
    PbCl4 (l) 329.3
    PbO₂ (s) 277.4 68.6 217.33
    Litio      
    Li (s) 0 29.12 0
    Li+ (g) 685.783
    LiOH (s) 484.93 42.8 438.95
    LiOH (aq) 508.48 2.8 450.58
    LiCl (s) 408.701 59.33 384.37
    Magnesio      
    Mg (s) 0 32.68 0
    Mg²+ (aq) 466.85 138.1 454.8
    MgCl₂ (g) 400.4
    MgCl₂ (s) 641.32 89.62 591.79
    MgCl₂ (aq) 801.15 25.1 717.1
    MgO (s) 601.70 26.94 569.43
    Mg (OH) ₂ (s) 924.54 63.18 833.51
    MG (s) 346 50.33 341.8
    MgSO4 (s) 1284.9 91.6 1170.6
    MgCO₃ (s) 1095.8 65.7 1012.1
    Mercurio      
    Hg (l) 0 76.02 0
    HgCl₂ (s) 224.3 146 178.6
    HgO (s, rojo) 90.83 70.9 58.539
    HgS (s, rojo) 58.2 82.4 50.6
    Níquel      
    Ni (s) 0 29.87 0
    NiO (s) 239.7 37.99 211.7
    NiCl₂ (s) 305.332 97.65 259.032
    Nitrógeno      
    N₂ (g) 0 191.61 0
    N₂ (aq) 10.8
    N (g) 472.704 153.298 455.53
    NH₃ (g) 46.11 192.45 16.45
    NH₃ (ac) 80.29 111.3 26.50
    NH4+ (aq) 132.51 113.4 79.31
    N₂H4 (l) 50.63 121.21 149.34
    NH4Cl (s) 314.43 94.6 202.87
    NH4Cl (aq) 299.66 169.9 210.52
    NH4NO₃ (s) 365.56 151.08 183.87
    NH4NO₃ (aq) 339.87 259.8 190.56
    NO (g) 90.25 210.761 86.55
    NO₂ (g) 33.18 240.06 51.31
    N₂O (g) 82.05 219.85 104.20
    N₂O4 (g) 9.16 304.29 97.89
    N₂ O4 (l) 19.50 209.2 97.54
    NOCl (g) 51.71 261.69 66.08
    HNO₃ (l) 174.10 155.60 80.71
    HNO₃ (g) 135.06 266.38 74.72
    HNO₃ (aq) 207.36 146.4 111.25
    NO3- (aq) 205.0 146.4 108.74
    NF₃ (g) 124.7 260.73 83.2
    Oxígeno†      
    O₂ (g) 0 205.138 0
    O₂ (aq) 11.7 110.9 16.4
    O (g) 249.170 161.055 231.731
    O₃ (g) 142.7 238.93 163.2
    OH- (aq) 229.994 10.75 157.244
    Fosforo      
    P₃ (s, blanco) 0 164.36 0
    P₃ (s, rojo) 70.4 91.2 48.4
    P (g) 314.64 163.193 278.25
    PH₃ (g) 5.4 310.23 13.4
    PCl₃ (g) 287.0 311.78 267.8
    PCl₃ (l) 319.7 217.1 272.3
    PCl5 (s) 443.5
    P4O₁ (s) 2984.0 228.86 2697.7
    H3PO4 (s) 1279 110.5 1119.1
    Potasio      
    K (s) 0 64.18 0
    KF (s) 567.27 66.57 537.75
    KCl (s) 436.747 82.59 409.14
    KCl (ac) 419.53 159.0 414.49
    KBr (s) 393.798 95.90 380.66
    KI (s) 327.900 106.32 324.892
    KClO₃ (s) 397.73 143.1 296.25
    KOH (s) 424.764 78.9 379.08
    KOH (aq) 482.37 91.6 440.5
    Silicio      
    Si (s) 0 18.83 0
    SiBr4 (l) 457.3 277.8 443.8
    SiC (s) 65.3 16.61 62.8
    SiCl4 (g) 657.01 330.73 616.98
    SiH4 (g) 34.3 204.62 56.9
    Tamiz (g) 1614.94 282.49 1572.65
    SiO₂ (s, cuarzo) 910.94 41.84 856.64
    Plata      
    Ag (s) 0 42.55 0
    Ag+ (aq) 105.579 72.68 77.107
    Ag₂O (s) 31.05 121.3 11.2
    AgCl (s) 127.068 96.2 109.789
    AGi (s) 61.84 115.5 66.19
    AGn₃ (s) 620.60 99.22 591.0
    AgNO₃ (s) 124.39 140.92 33.41
    AgNO₃ (aq) 101.8 219.2 34.16
    Sodio      
    Na (s) 0 51.21 0
    Na (g) 107.32 153.712 76.761
    Na+ (g) 609.358
    Na+ (aq) 240.12 59.0 261.905
    NaF 573.647 51.46 543.494
    NaF (aq) 572.75 45.2 540.68
    NaCl (s) 411.153 72.13 384.138
    NaCl (g) 176.65 229.81 196.66
    NaCl (aq) 407.27 115.5 393.133
    NaBr (s) 361.062 86.82 348.983
    NaBr 361.665 141.4 365.849
    NaI (s) 287.78 98.53 286.06
    NaI (aq) 295.31 170.3 313.47
    NaOH (s) 425.609 64.455 379.484
    NaOH (aq) 470.114 48.1 419.15
    NaClO₃ (s) 365.774 123.4 262.259
    NaHCO₃ (s) 950.81 101.7 851.0
    Na2CO₃ (s) 1130.68 134.98 1044.44
    Na2SO4 (s) 1387.08 149.58 1270.16
    Azufre      
    S (s, monoclínico) 0.33
    S (s, rómbico) 0 31.80 0
    S (g) 278.805 167.821 238.250
    S²⸺- (aq) 33.1 14.6 85.8
    S₂Cl₂ (g) 18.4 331.5 31.8
    SF6 (g) 1209 291.82 1105.3
    SF4 (g) 774.9 292.03 731.3
    H2S (g) 20.63 205.79 33.56
    H2S (ac) 39.7 121 27.83
    HS- (aq) 17.6 62.8 12.08
    SO₂ (g) 296.830 248.22 300.194
    SO₃ (g) 395.72 256.76 371.06
    SoCl₂ (g) 212.5 309.77 198.3
    SO4²ð (aq) 909.27 20.1 744.53
    H2SO4 (l) 813.989 156.904 690.003
    H2SO4 (aq) 909.27 20.1 744.53
    HSO4- (aq) 887.34 131.8 755.91
    Estaño      
    Sn (s, blanco) 0 51.55 0
    Sn (s, gris) 2.09 44.14 0.13
    SnCl₂ (s) 325.1
    SnCl4 (l) 511.3 258.6 440.1
    SnCl4 (g) 471.5 365.8 432.2
    SnO₂ 580.7 52.3 519.6
    Titanio      
    Ti (s) 0 30.63 0
    TiCl4 (l) 804.2 252.34 737.2
    TiCl4 (g) 763.2 354.9 726.7
    TiO₂ (s) 939.7 49.92 884.5
    Uranio      
    U (s) 0 50.21 0
    UO₂ (s) 1084.9 77.03 1031.7
    UO₃ (s) 1223.8 96.11 1145.9
    UF4 (s) 1914.2 151.67 1823.3
    UF6 (g) 2147.4 377.9 2063.7
    UF6 (s) 2197.0 227.6 2068.5
    Zinc      
    Zn (s) 0 41.63 0
    ZnCl₂ (s) 415.05 111.46 369.398
    ZnO (s) 348.28 43.64 318.3
    ZnS (s, esfalerita) 205.98 57.7 201.29

    De Wagman, D. D., Evans, W. H., Parker, V. B., Schumm, R. H., Halow, I., Bailey, S. M., Churney, K. L., y Nuttall, R., Revista de Datos de Referencia Físicos y Químicos, Vol. 11, Supl. 2, 1982.
    Muchos compuestos que contienen hidrógeno y oxígeno se enumeran solo bajo otros elementos.


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