22.3: Las constantes de formación para los iones complejos
- Page ID
- 1988
\( \newcommand{\vecs}[1]{\overset { \scriptstyle \rightharpoonup} {\mathbf{#1}} } \) \( \newcommand{\vecd}[1]{\overset{-\!-\!\rightharpoonup}{\vphantom{a}\smash {#1}}} \)\(\newcommand{\id}{\mathrm{id}}\) \( \newcommand{\Span}{\mathrm{span}}\) \( \newcommand{\kernel}{\mathrm{null}\,}\) \( \newcommand{\range}{\mathrm{range}\,}\) \( \newcommand{\RealPart}{\mathrm{Re}}\) \( \newcommand{\ImaginaryPart}{\mathrm{Im}}\) \( \newcommand{\Argument}{\mathrm{Arg}}\) \( \newcommand{\norm}[1]{\| #1 \|}\) \( \newcommand{\inner}[2]{\langle #1, #2 \rangle}\) \( \newcommand{\Span}{\mathrm{span}}\) \(\newcommand{\id}{\mathrm{id}}\) \( \newcommand{\Span}{\mathrm{span}}\) \( \newcommand{\kernel}{\mathrm{null}\,}\) \( \newcommand{\range}{\mathrm{range}\,}\) \( \newcommand{\RealPart}{\mathrm{Re}}\) \( \newcommand{\ImaginaryPart}{\mathrm{Im}}\) \( \newcommand{\Argument}{\mathrm{Arg}}\) \( \newcommand{\norm}[1]{\| #1 \|}\) \( \newcommand{\inner}[2]{\langle #1, #2 \rangle}\) \( \newcommand{\Span}{\mathrm{span}}\)
| Las constantes de formación para los iones complejos | |
|---|---|
| El equilibrio | Kf |
| \(\ce{Al^3+ + 6F- ⇌ [AlF6]^3-}\) | 7 × 1019 |
| \(\ce{Cd^2+ + 4NH3 ⇌ [Cd(NH3)4]^2+}\) | 1.3 × 107 |
| \(\ce{Cd^2+ + 4CN- ⇌ [Cd(CN)4]^2-}\) | 3 × 1018 |
| \(\ce{Co^2+ + 6NH3 ⇌ [Co(NH3)6]^2+}\) | 1.3 × 105 |
| \(\ce{Co^3+ + 6NH3 ⇌ [Co(NH3)6]^3+}\) | 2.3 × 1033 |
| \(\ce{Cu+ + 2CN ⇌ [Cu(CN)2]-}\) | 1.0 × 1016 |
| \(\ce{Cu^2+ + 4NH3⇌[Cu(NH3)4]^2+}\) | 1.7 × 1013 |
| \(\ce{Fe^2+ + 6CN- ⇌[Fe(CN)6]^4-}\) | 1.5 × 1035 |
| \(\ce{Fe^3+ + 6CN- ⇌[Fe(CN)6]^3-}\) | 2 × 1043 |
| \(\ce{Fe^3+ + 6SCN- ⇌[Fe(SCN)6]^3-}\) | 3.2 × 103 |
| \(\ce{Hg^2+ + 4Cl- ⇌[HgCl4]^2-}\) | 1.1 × 1016 |
| \(\ce{Ni^2+ + 6NH3⇌[Ni(NH3)6]^2+}\) | 2.0 × 108 |
| \(\ce{Ag+ + 2Cl- ⇌[AgCl2]-}\) | 1.8 × 105 |
| \(\ce{Ag+ + 2CN- ⇌[Ag(CN)2]-}\) | 1 × 1021 |
| \(\ce{Ag+ + 2NH3⇌[Ag(NH3)2]+}\) | 1.7 × 107 |
| \(\ce{Zn^2+ + 4CN- ⇌[Zn(CN)4]^2-}\) | 2.1 × 1019 |
| \(\ce{Zn^2+ + 4OH- ⇌[Zn(OH)4]^2-}\) | 2 × 1015 |
| \(\ce{Fe^3+ + SCN- ⇌[Fe(SCN)]^2+}\) | 8.9 × 102 |
| \(\ce{Ag+ + 4SCN- ⇌[Ag(SCN)4]^3-}\) | 1.2 × 1010 |
| \(\ce{Pb^2+ + 4I- ⇌[PbI4]^2-}\) | 3.0 × 104 |
| \(\ce{Pt^2+ + 4Cl- ⇌[PtCl4]^2-}\) | 1 × 1016 |
| \(\ce{Cu^2+ + 4CN⇌[Cu(CN)4]^2-}\) | 1.0 × 1025 |
| \(\ce{Co^2+ + 4SCN- ⇌[Co(SCN)4]^2-}\) | 1 × 103 |