Síntesis de epóxidos. Reacción de Prileschajew

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6 feb 2021
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Uno de los métodos más utilizados para la formación de epóxidos (éteres ciclicos u oxiranos) es la oxidación de alquenos mediante la reacción de Prileschajew.

La reacción de Prileschajew, es una reacción concertada y se da con peroxiácidos (RCO3H), el más utilizado es el ácido metacloroperbenzoico (MCPBA). La reacción procede con la retención de configuración del alqueno.

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